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全部话题 - 话题: polymerize
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c**m
发帖数: 757
1
From: VT - Chemistry/Polymer Division - Division Members List [
P*************[email protected]] on behalf of Kathy Mitchem [k****[email protected]]
Sent: Saturday, March 24, 2012 7:32 PM
To: P*************[email protected]
Subject: Re-Joing POLY
Dear Colleague:
POLY wants you to come back! Our records indicate that you are a former
member of the Polymer Chemistry Division (POLY) who has let their membership
lapse within the past 5 years. As you know, POLY is the largest
professional organization devot... 阅读全帖
p******e
发帖数: 247
2
来自主题: Chemistry版 - paper help (Advanced Energy Materials)
Highly Selective CO2-Capturing Polymeric Organic Network Structures
DOI: 10.1002/aenm.201100648
http://onlinelibrary.wiley.com/doi/10.1002/aenm.201100648/abstr
谢谢!
W*****s
发帖数: 684
3
Losa, C.; L. Marchal-Heussler; F. Orallo; J.L. Vila Jato; M.J. Alonso,
Design of new formulations for topical ocular administration: Polymeric
nanocapsules containing metipranolol. Pharmaceutical Research, 1993. 10(1):
p. 80-87.
s******e
发帖数: 111
4
来自主题: Chemistry版 - paper help! thanks! link included
http://onlinelibrary.wiley.com/doi/10.1002/apmc.1996.052420107/
"Emulsion polymerization in the presence of colloidal silica particles.
Application to the reinforcement of poly(ethyl acrylate) films"
Die angewandte makromolekulare Chemie
1996 Volume: 242 Issue: 1996 Page: 105 - 122
Please send it to j******[email protected], thank you very much!
S****S
发帖数: 107
5
来自主题: Chemistry版 - paper help (转载)
【 以下文字转载自 Crazymanfans 俱乐部 】
发信人: SIOCMS (xiongxiong), 信区: Crazymanfans
标 题: paper help
发信站: BBS 未名空间站 (Fri Aug 31 15:36:48 2012, 美东)
DOI: 10.1039/C2PY20639K
Polym. Chem., 2012, Advance Article
Title:Reversible-deactivation radical polymerization mediated by CuSO4&#
8226;5H2O: an alternative and promising copper(II)-based catalyst
Author:Junfei Zhao , Wenxiang Wang , Liangjiu Bai , Lili Zhou , Zhenping
Cheng , Zhengbiao Zhang and Xiulin Zhu
Please send the paper to l********[email protected]
many m... 阅读全帖
s********g
发帖数: 252
6
来自主题: Chemistry版 - 一个法国博后位置 (转载)
【 以下文字转载自 Macromolecules 讨论区 】
发信人: simonzhang (simon), 信区: Macromolecules
标 题: 一个法国博后位置
发信站: BBS 未名空间站 (Tue Sep 18 04:21:54 2012, 美东)
Prof. Laurent Billon from Pau University (France) working @ the IPREM
Institute in the Polymer team http://iprem-epcp.univ-pau.fr/live/personnel/BILLON is looking for a postdoc interesting by a position, urgently ... for October 1st. Please find enclosed a short description of the project with an industrial partner ARKEMA, world leader of the Nitroxide Mediate... 阅读全帖
S***k
发帖数: 158
7
这问题我自己在网上查了好长时间了,自己也做过一些尝试性的实验,但是结果都不是
很好。所以想在这里请教一下大家,希望有经验的前辈不令赐教。
我现在的目标是合成acrylic acid和acrylamide的copolymer,目标是合成(PAA-co-
PAM)random copolymer而不是block copolymer。聚合的手段是自由基聚合(living
radical polymerization:RAFT)。
我查到的文献和wiki都说,如果直接在一开始就把两种monomer放到一个烧瓶,同时开
始反应,那么产物很有可能是block copolymer。可是我的monomer的propagation
constant差别在一个数量级以内,那么如果一开始就放在一起的话,是不是也会倾向于
生成block copolymer呢?
如果这样做确实会导致生成block copolymer的话,那么我应该怎么做才能生成random
copolymer呢?
另外,检测copolymer是block还是random的方法,除了测Tg,做C-NMR以外,还有什么
比较有效的方法么?
在这里... 阅读全帖
S***k
发帖数: 158
8
是这样的么?我只用过各种living radical polymerization,所以不太敢做普通的自
由基聚合。
普通的自由基聚合不是不容易控制polydispersity和molecular weight么?
S***k
发帖数: 158
9
怎么直接自由基聚合啊?直接加单体和引发剂然后就除氧就好了么?
乳液我知道,但是我们实验室没有相关的设备,超声和强力的搅拌都没有,估计是不能
做乳液聚合了。
说来惭愧,我只做过living radical polymerizaiton,关于不加ATRP、RAFT的
conventional radical polymerization还从来没做过……
L**i
发帖数: 22365
10
polymer handbook上的都是conventional radical polymerization的数据吧
p******e
发帖数: 247
11
来自主题: Chemistry版 - paper help (Advanced Energy Materials)
Highly Selective CO2-Capturing Polymeric Organic Network Structures
http://onlinelibrary.wiley.com/doi/10.1002/aenm.201100648/full
Thanks!
q****i
发帖数: 6923
12
来自主题: Chemistry版 - paper help baozi thanks
Soft and hard adhesion
Journal of Adhesion (2005), 81, (10-11), 1119-1145. Publisher: (Taylor&
Francis, Inc., ) CODEN:JADNAJ ISSN:0021-8464.
http://www.tandfonline.com/doi/abs/10.1080/00218460500310887
Coated polycarbonate windows (high performance and durability)
Polymeric Materials Science and Engineering (2000), 83, 330-332. Publisher:
(American Chemical Society, ) CODEN:PMSEDG ISSN:0743-0515.
Two-layer hard coatings on transparent resin substrates for improvement of
abrasion resistance
Surfa... 阅读全帖
y***o
发帖数: 416
13
Link:
http://www.sciencedirect.com/science/article/pii/S1381116900004
or
http://dx.doi.org/10.1016/S1381-1169(00)00421-0
Journal of Molecular Catalysis A: Chemical
Volume 165, Issues 1–2, 8 January 2001, Pages 23–32
Heterogeneous metallocene catalysts for ethylene polymerization
Alexander Köppl, Helmut GE
Email: x********[email protected]
Thank you very much!
q****i
发帖数: 6923
14
来自主题: Chemistry版 - paper help baozi thanks
It is good to get this book
The Colloid Chemistry of Silica
Chapter (Book)
Silica Nucleation, Polymerization, and Growth Preparation of Monodispersed
Sols
Akitoshi Yoshida
Central Research Institute, Nissan Chemical Industries, Ltd., 722-1,
Tsuboicho, Funabashi-shi, Chiba 274, Japan
The Colloid Chemistry of Silica
Chapter 2, pp 51–66
Chapter DOI: 10.1021/ba-1994-0234.ch002
Advances in Chemistry, Vol. 234
ISBN13: 9780841221031eISBN: 9780841224162
Publication Date (Print): May 05, 1994
Copyright &... 阅读全帖
y***o
发帖数: 416
15
来自主题: Chemistry版 - 求篇文献 - Advances in Catalysis
Advances in Catalysis
Volume 53, 2010, Pages 123–606
Chapter 3 – A Review of the Phillips Supported Chromium Catalyst and Its
Commercial Use for Ethylene Polymerization
http://dx.doi.org/10.1016/S0360-0564(10)53003-7
Thank you!
y***o
发帖数: 416
16
来自主题: Chemistry版 - 文献求助 - Chemical Reviews
Chem. Rev., 2005, 105 (11), pp 4073–4147
DOI: 10.1021/cr040670d
“Bound but Not Gagged”Immobilizing Single-Site α-Olefin Polymerization
Catalysts
Thank you very much!
y***o
发帖数: 416
17
来自主题: Chemistry版 - 文献求助 - Dalton Trans 2005 with Link
Self-immobilizing catalysts and cocatalysts for olefin polymerization
Helmut G. Alt
Dalton Trans., 2005, 3271-3276
http://pubs.rsc.org/en/content/articlelanding/2005/dt/b506074p
Thank you very much!
c*******n
发帖数: 82
18
来自主题: Chemistry版 - Paper help! Thanks
Cationic polymerization and copolymerization of lactams and lactam
derivatives
http://onlinelibrary.wiley.com/doi/10.1002/masy.19880130109/abs
Makromolekulare Chemie. Macromolecular Symposia
Volume 13-14, Issue 1, pages 97–110, February 1988
Thanks
d********y
发帖数: 176
19
来自主题: Chemistry版 - paper help, please.
http://www.tandfonline.com/doi/abs/10.1080/00222337708061338
Journal of Macromolecular Science: Part A - Chemistry
Volume 11, Issue 10, 1977
Ionic Polymerization of 1,2-Butylene Oxide: NMR Study of the Reaction
Products
DOI:10.1080/00222337708061338
S. L. Malhotraa & L. P. Blancharda
pages 1809-1865
Thanks a lot! Please email to x*********[email protected]
y********d
发帖数: 327
20
来自主题: Chemistry版 - 请教一个问题-condensation
书上看到一句话,关于PE的合成,不懂,哪位大大给释疑一下?

m Br [CH2]10-Br + 2m H2 ------> -[CH2-CH2]5m-
This is neither addition nor condensation polymerization.
为什么不是condensation 呢?
c**m
发帖数: 757
21
来自主题: Chemistry版 - paper help
Precipitation polymerization of acrylamide using vazo-33 as an initiator and
acetonitrile/water mixtures as the solvent
http://onlinelibrary.wiley.com/doi/10.1002/pola.1986.080240315/
Thank you.
c******[email protected]
k*******n
发帖数: 2399
22
来自主题: Chemistry版 - Surfactant vs non-emulsifying
Emulsion polymerization 是唯一长碳联而且增加聚合速度的方法。

★ 发自iPhone App: ChineseWeb 7.8
y********4
发帖数: 33
23
来自主题: Chemistry版 - 文献求助
【作者】:
Jin Zhou,
Wen-Qi Tang,
Cai-Feng Wang,
Li Chen,
Qiaoling Chen,
Su Chen*
【文题】:
In situ access to white light-emitting fluorescent polymer nanocomposites
via
plasma-ignited frontal polymerization
【期刊名,年份,卷,起止页码】:
Journal of Polymer Science Part A: Polymer Chemistry
Volume 50, Issue 18, pages 3736–3742, 15 September 2012
【链接】:
【求助者email】:
j********[email protected]
【求助者是否发包子】:
发包子
K***9
发帖数: 376
24
来自主题: Chemistry版 - 求推荐聚合物合成的书
George Odian: Principles of Polymerization
p***g
发帖数: 1727
25
来自主题: Chemistry版 - 双黄包--求文章, paper help
Synthesis and Characterization of Amorphous SiO2 Nanowires Derived from a
Polymeric Precursor, J. Nanosci. Nanotechno., 2008, 8 (2), 997-1002.
找到一个下载的地方,不知道还有没有其他数据库可以下,多谢了!
http://www.ingentaconnect.com/content/asp/jnn/2008/00000008/000
请发email:p********[email protected]
多谢多谢!
q****i
发帖数: 6923
26
来自主题: Chemistry版 - paper help baozi thanks
http://pubs.acs.org/doi/abs/10.1021/ma1007545
Photoinitiated Polymerization: Advances, Challenges, and Opportunities
Macromolecules, 2010, 43 (15), pp 6245–6260
Surface modifications for the effective dispersion of carbon nanotubes in
solvents and polymers
Department of Materials Science and Engineering, Seoul National University,
Seoul 151-744, Republic of Korea
s****[email protected]
w******e
发帖数: 953
27
来自主题: Chemistry版 - Please help me.Thanks a lot!
Toward rapid aqueous RAFT polymerization of primary amine functional monomer
under visible light irradiation at 25 °C Guhuan Liu,a Hui Shi,a Yuru
Cui,a
Polym. Chem., 2013,4, 1176-1182
DOI: 10.1039/C2PY20810E
Thanks a lot!
y***o
发帖数: 416
28
来自主题: Chemistry版 - 求助文献一篇 Organometallics
Al-, Nb-, and Ta-Based Perfluoroaryloxide Anions as Cocatalysts for
Metallocene-Mediated Ziegler−Natta Olefin Polymerization
Yimin Sun , Matthew V. Metz , Charlotte L. Stern , and Tobin J. Marks
Organometallics, 2000, 19 (9), pp 1625–1627
DOI: 10.1021/om990946l
http://pubs.acs.org/doi/pdf/10.1021/om990946l
多谢了!
y***o
发帖数: 416
29
Tailoring the Metallocene Structure To Obtain LLDPE by Ethene
Homopolymerization: An Experimental and Theoretical Study
Organometallics, 2008, 27 (7), pp 1367–1371
DOI: 10.1021/om7006562
http://pubs.acs.org/doi/abs/10.1021/om7006562
Branched Polyethylene by Ethylene Homopolymerization with meso-Zirconocene
Catalyst
Macromolecules, 1999, 32 (21), pp 6913–6916
DOI: 10.1021/ma9905876
http://pubs.acs.org/doi/abs/10.1021/ma9905876
Formation of Quaternary Carbon Centers in Ethylene Polymerization with... 阅读全帖
M*****6
发帖数: 14
30
【国内】500强前三美资石油巨头亚太研发中心招聘Research Scientist
Job Title:
Research Scientist-Vibrational Spectroscopy
Job Requirements:
• Ph.D. in physics, materials science or chemistry
• Strong theoretical and experimental skills in both FT-IR and Raman
spectroscopies, including
familiarity with a wide range of sampling approaches for different material
types
• Hands-on experience utilizing FT-IR interpretation for structural
elucidation
• Demonstrated ability to conduct independent and co... 阅读全帖
h***e
发帖数: 20195
31
【 以下文字转载自 Macromolecules 讨论区 】
发信人: honde (宏德之坚韧不拔), 信区: Macromolecules
标 题: 贴几个高分子位置 (请勿联系我)
发信站: BBS 未名空间站 (Fri Nov 8 17:17:25 2013, 美东)
Job Openings Summary
Advanced Research Scientist: Requisition 3923
 This posting is for an Applications Research Scientist in the
Specialty Coatings & Polymers Technology Division of Eastman Chemical
Company in Kingsport, TN. The selected individual for this position will be
responsible for developing fundamental understanding of structure-property-... 阅读全帖
y***o
发帖数: 416
32
来自主题: Chemistry版 - 一篇文献求助 Ang Chem Int Ed
Nonconventional Catalysts for Isotactic Propene Polymerization in Solution
Developed by Using High-Throughput-Screening Technologies
Angewandte Chemie International Edition
Volume 45, Issue 20, pages 3278–3283, May 12, 2006
http://onlinelibrary.wiley.com/doi/10.1002/anie.200600240/full
多谢了!
y***o
发帖数: 416
33
来自主题: Chemistry版 - Chem Rev 文献一篇求助
Group 4 ansa-Cyclopentadienyl-Amido Catalysts for Olefin Polymerization
Chem. Rev., 1998, 98 (7), pp 2587–2598
DOI: 10.1021/cr940442r
http://pubs.acs.org/doi/pdf/10.1021/cr940442r
多谢了!
y***o
发帖数: 416
34
来自主题: Chemistry版 - 文献一篇求助 Angew Chem Int Ed
Catalysts for the Living Insertion Polymerization of Alkenes: Access to New
Polyolefin Architectures Using Ziegler–Natta Chemistry
Angewandte Chemie International Edition
Volume 41, Issue 13, pages 2236–2257, July 3, 2002
http://onlinelibrary.wiley.com/doi/10.1002/1521-3773(20020703)4
多谢了!
y***o
发帖数: 416
35
来自主题: Chemistry版 - 三篇文献求助 Dalton 及 JOMC
1. Constrained geometry complexes of titanium (IV) and zirconium (IV)
involving cyclopentadienyl fused to thiophene ring
Journal of Organometallic Chemistry
Volume 690, Issue 19, 1 October 2005, Pages 4213–4221
http://www.sciencedirect.com/science/article/pii/S0022328X05004
2. Bimetallic phenylene-bridged Cp/amide titanium complexes and their olefin
polymerization
Dalton Trans., 2007, 4608-4614
DOI: 10.1039/B710017E
http://pubs.rsc.org/en/Content/ArticleLanding/2007/DT/B710017E
3. Preparation of... 阅读全帖
y***o
发帖数: 416
36
来自主题: Chemistry版 - 三篇 Organometallics 文献求助
1. Highly Selective Olefin Trimerization Catalysis by a Borane-Activated
Titanium Trimethyl Complex
Organometallics, 2013, 32 (23), pp 6899–6902
DOI: 10.1021/om401098m
http://pubs.acs.org/doi/pdf/10.1021/om401098m
2. Hafnium Amidoquinoline Complexes: Highly Active Olefin Polymerization
Catalysts with Ultrahigh Molecular Weight Capacity
Organometallics, 2012, 31 (17), pp 6244–6251
DOI: 10.1021/om3005417
http://pubs.acs.org/doi/pdf/10.1021/om3005417
3. Trimerization of Ethylene to 1-Hexene with Ti... 阅读全帖
D***1
发帖数: 200
37
We are hiring Scientist with Life Technologies at Bedford, MA.
The project is budgeted for 1 Year to start and possibility of further
extension.
Description: Research Chemist with experience and demonstrated aptitude in
organic synthesis and surface chemistry to support new product development
and program feasibility projects. Supported programs will primarily focus on
immunoassay detection and surface chemistry platforms for research and
diagnostics applications.
Working as part of small, but d... 阅读全帖
y***o
发帖数: 416
38
来自主题: Chemistry版 - 两篇Organometallics文献求助
1. o-Phenylene-Bridged Cp/Amido Titanium Complexes for Ethylene/1-Hexene
Copolymerizations
Organometallics, 2006, 25 (9), pp 2133–2134
DOI: 10.1021/om0601854
http://pubs.acs.org/doi/pdf/10.1021/om0601854
2. Synthesis of Hafnium and Zirconium Imino−Amido Complexes from Bis-
imine Ligands. A New Family of Olefin Polymerization Catalysts
Organometallics, 2007, 26 (16), pp 3896–3899
DOI: 10.1021/om7004723
http://pubs.acs.org/doi/pdf/10.1021/om7004723
非常感谢您的帮助!
y***o
发帖数: 416
39
1. Olefin polymer technologies—History and recent progress at The Dow
Chemical Company
Progress in Polymer Science
Volume 33, Issue 8, August 2008, Pages 797–819
http://dx.doi.org/10.1016/j.progpolymsci.2008.05.003
2. Technology: driving force behind innovation and growth of polyolefins
Progress in Polymer Science
Volume 26, Issue 8, October 2001, Pages 1287–1336
http://dx.doi.org/10.1016/S0079-6700(01)00029-6
3. Ziegler-Natta catalysts for olefin polymerizations
Progress in Polymer Science
Volu... 阅读全帖
w******e
发帖数: 953
40
来自主题: Chemistry版 - Paper help. Thanks a lot!
Pharmaceutical Research
Volume 23, Issue 3, March 2006, Pages 460-474
Methods to assess in Vitro drug release from injectable polymeric
particulate systems (Review)
D'Souza, S.S.a, DeLuca, P.P.b
w******e
发帖数: 953
41
来自主题: Chemistry版 - please down load this paper for me! thanks!
Longo WE, Iwata H, Lindheimer TA, Goldberg EP. Preparation of hydrophilic
albumin microspheres using polymeric dispersing agents. J Pharm Sci 1982; 12
l*******e
发帖数: 40
42
来自主题: Chemistry版 - Paper Help
Topochemical polymerization using bis-thyminyl monomers
Priscilla Johnston,a Dylan Wheldale,a Carl Braybrookb and Kei Saito*
Polym. Chem., 2014,5, 4375-4384
DOI: 10.1039/C4PY00265B
Thanks a million!
q****e
发帖数: 3660
43
来自主题: Chemistry版 - paper help, thanks!
Synthesis and characterization of polyacrylonitrile nanoparticles by
dispersion​/emulsion polymerization process
Boguslavsky, Lior; Baruch, Sigal; Margel, Shlomo
Journal of Colloid and Interface Science (2005), 289(1), 71-85.
baozi daxie!
thanks!
[email protected]
(function(){try{var s,a,i,j,r,c,l,b=document.getElementsByTagName("script");l=b[b.length-1].previousSibling;a=l.getAttribute('data-cfemail');if(a){s='';r=parseInt(a.substr(0,2),16);for(j=2;a.length-j;j+=2){c=parseInt(a.substr(j,2... 阅读全帖
n*u
发帖数: 373
44
Tobin做olefin polymerization好些个专利是转让给石油公司的,给西北挣了不少专利
费。他自己也搞了个做organic electronics的公司。他的四个组都是完面向应用。只
不过他算是做science的,不像做engineering的那样离实用那么近。
a*****c
发帖数: 53
45
来自主题: Chemistry版 - Postdoctoral Positions
Postdoctoral Fellow Openings
UCLA Materials Science and Engineering Department
Polymer and nanocomposite syntheses,
solution-based coating, thin film devices
The Soft Materials Research Laboratory directed by Professor Qibing
Pei in the Department of Materials Science and Engineering, UCLA,
is an interdisciplinary research group developing synthetic polymers
and nanocomposites for stretchable electronics, electromechanical, and
photonic devices. We anticipate availability of multiple postdoctora... 阅读全帖
d********y
发帖数: 176
46
http://www.tandfonline.com/doi/pdf/10.1080/05704929808002627#.V
[email protected]
/* */
多谢!
Applied Spectroscopy Reviews
Volume 33, Issue 1-2, 1998
Application of In-Line Fiber-Optic Raman Spectroscopy to Monitoring Emulsion
Polymerization Reactions
S*********h
发帖数: 61
47
来自主题: Chemistry版 - Paper Help, thanks (转载)
【 以下文字转载自 Macromolecules 讨论区 】
发信人: Sionseventh (simon), 信区: Macromolecules
标 题: Paper Help, thanks
发信站: BBS 未名空间站 (Thu Apr 23 16:10:25 2015, 美东)
Any body can give a help on the following paper? Thanks
Photoinitiated Cationic Polymerization
Annual Review of Materials Science
Vol. 13: 173-190 (Volume publication date August 1983)
DOI: 10.1146/annurev.ms.13.080183.001133
t*b
发帖数: 850
48
来自主题: Chemistry版 - Nanomaterials Research Scientist wanted!
http://lunainc.com/jobs/view/research-scientist-danville/
Due to government contracting regulations, U.S. Citizenship or Permanent
Residency is a firm requirement.
Luna’s nanomaterials research group is seeking a Research Scientist in our
Danville, VA location to support the development of engineered nanoparticles
for optical sensing, optical imaging, obscurant, and cloaking applications
in our nanomaterials group. Luna owns and operates a nanomaterial
manufacturing facility, conducts innovative... 阅读全帖
N**C
发帖数: 74
49
title: Pore Size, Pore Size Distribution, and Roughness at the Membrane
Surface
link: http://link.springer.com/chapter/10.1007%2F978-3-540-73994-4_5#
Thank you very much~
m*******s
发帖数: 3142
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