d****i 发帖数: 360 | 1 Synthesis by AGET ATRP of degradable nanogel precursors for in situ
formation of nanostructured hyaluronic acid hydrogel. Bencherif, S.A.,
Washburn, N.R., Matyjaszewski, K. Biomacromolecules, Volume 10, Issue 9, 14
September 2009, Pages 2499-2507
Thanks a lot! |
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d****i 发帖数: 360 | 2 Synthesis by AGET ATRP of degradable nanogel precursors for in situ
formation of nanostructured hyaluronic acid hydrogel. Bencherif, S.A.,
Washburn, N.R., Matyjaszewski, K. Biomacromolecules, Volume 10, Issue 9, 14
September 2009, Pages 2499-2507
Thanks a lot! |
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j********1 发帖数: 17 | 4 的确是的,王锦山真要争ATRP,自己独立出去做FACULTY后可以单搞,独立后优秀的工
作出来学界自然承认他的位置。就好比老钱搞钙离子荧光探针,差不多也是在博士及博
士后期间做出来的,自己独立后又做出来格外重要的贡献(FURA-2),现在学界谈calcium
indicator基本只谈他的贡献,没人谈他博后老板。 |
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w********h 发帖数: 12367 | 5 现在开始回来做也来得及。
再有个大突破,解决了ATRP的催化剂污染以及在国内实现了工业化,
一头一尾,王锦山将牢牢锁定诺贝尔奖。
//祝愿老王这次回国成绩显著! |
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z**u 发帖数: 48 | 6 开场了
题目:ATRP的发现与发展
报告人:王锦山博士
时间:11月6日 上午9:40
地点:微尺度国家实验室一楼科技展厅 |
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s**m 发帖数: 4340 | 8 每篇给3个包子,如果全都找全就一共给10个包子。
谢谢您的帮助!
我的email: c*************[email protected]
Li, K. et al. Dual modification of M13 bacteriophage and its application for
cell imaging. PMSE Preprints (2009), 101 1198-1199.
Li, T. et al. Synthesis of bionanoparticle-polymer conjugates via in situ
atom transfer radical polymerization (ATRP) reaction. PMSE Preprints (2007)
, 97 621-622.
Li, S. et al. Preparation and characterization of polypyrrole nanodisc
templated by tobacco mosaic virus. PMSE Preprints (2007), 96 |
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y***k 发帖数: 57 | 9 No one know?
Update: Company with experience in ATRP polymerization is also OK! |
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j*********5 发帖数: 6221 | 11 传统意义的化学要很多年验证其应用性
比如D-A反应,隔了多少年才发奖啊,还有suzuki,heck,这都做了多少年拉
ATRP不知道要等多少年 |
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x********e 发帖数: 1064 | 12 Polymer Bulletin
Volume 59, Number 2, 195-206, DOI: 10.1007/s00289-007-0754-0
Synthesis of poly( N -isopropylacrylamide) by ATRP using a fluorescein-based
initiator
Xiaoju Lu, Lifen Zhang, Lingzhi Meng and Yunhai Liu
Please send to my email:x********[email protected]
Thanks |
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a**r 发帖数: 224 | 14 start up
开会的时候曾经碰到
前景的话,得看有多大市场,有多少VC投入 |
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S***k 发帖数: 158 | 16 怎么直接自由基聚合啊?直接加单体和引发剂然后就除氧就好了么?
乳液我知道,但是我们实验室没有相关的设备,超声和强力的搅拌都没有,估计是不能
做乳液聚合了。
说来惭愧,我只做过living radical polymerizaiton,关于不加ATRP、RAFT的
conventional radical polymerization还从来没做过…… |
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发帖数: 1 | 17 诚求审稿机会,
本人在日本取得硕博学位并有一年半博后经历,目前在美国继续博后工作,已有多次审稿
经验,最近在准备申请美国的绿卡,想继续积攒文章审稿数目,特诚求审稿机会。
主要研究方向有:
Biologically inspired materials;
Polymer biomaterials;
Surface modification;
Living radical polymerization (ATRP/RAFT);
Polymer nanoparticles and hydrogels;
Polymer therapeutics/Gene (RNA/protein) delivery systems;
Cell and material interactions;
Biosensor/biofuel cell;
Nanomedicine / Cancer therapy;
Bacterial, mammal cells and stem cells;
Laser scanning confocal microscopy;
Single cell analysis;
PDMS-b... 阅读全帖 |
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c*s 发帖数: 2145 | 18 现在是比较牛的, ATRP发了N多的文章,不过 开创者不是他。
据某博士后吹:化学界他能排在美国前50位。
【 在 pekwind (maxawei) 的大作中提到: 】
我看他去年的在macromolecules上的papers好多的说! |
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y****u 发帖数: 50 | 20 来自主题: Macromolecules版 - 有关ATRP I think the impurities will change the dn/dc of your polymer solution. I never
care the metal ions but I follow the purification method of
disolution-precipitation. |
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p*****d 发帖数: 40 | 21 来自主题: Macromolecules版 - 有关ATRP neutral aluminum column |
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c*s 发帖数: 2145 | 22 来自主题: Macromolecules版 - 有关ATRP thank you for answering so old question. hehe |
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p*****d 发帖数: 40 | 23 来自主题: Macromolecules版 - 有关ATRP i just happened to click "same author reading" and found your post. hehe
】 |
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p*****d 发帖数: 40 | 24 来自主题: Macromolecules版 - 有关ATRP also depends on the Tg of polymer ba. Did you succeed with viscous polymer?
Can you get rid of copper just by ppt?
】 |
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p**y 发帖数: 95 | 25 It is hot years ago.
But now, it is not so promising since no one
can really apply this technology to industry.
If such radical polymerization can not have
industry application, can you see any thing good
here? |
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y****u 发帖数: 50 | 27 After a rough reading, I know Living Radical/Carbocationic Polymerizations are
nothing. Polymer science and engineering, like many other disciplines, is
strongly market-oriented.
Why was there so much fanfare about ATRP in ACS Boston Meeting? |
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t***m 发帖数: 114 | 28 for ATRP and RAFT we follow different criteria
though both are not exact "living" polymerization.
maybe call it controlled polymerization is better. |
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c****n 发帖数: 134 | 29 hehe...are u talking about ATRP? |
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w********h 发帖数: 12367 | 30 of course not.
ATRP is one the most exciting findings in Polymer Chemistry after
Ziegler-Natta catalysts. |
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c****n 发帖数: 134 | 31 哦?活性阴离子聚合在ZIEGLER-NATTA之后吗?
好象ATRP的工业化前景尚不明朗。
而没有工业化产品,和垃圾无异。只是培养了一些科研人才而已。 |
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h****y 发帖数: 26 | 32 包括ATRP在内的各种Controlled radical polymerization的研究具有很广阔的前景,
决不是像你说得这样
and |
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t*******n 发帖数: 66 | 33 很高兴你想考北大的高分子专业. 首先一个问题是北大现在很多是硕博连读. 所以每年招
收的博士生很少. 现在说一下导师的情况.
液晶高分子方向: 周其风负责人.博导. 但现在具体是范星河在带领次组. 词组主要是高
分字合成合成.此组较大, 主要用自由机聚合和缩聚. 贾芯如领导的Dendrimer小组也包括
在这儿.
功能高分子: 李子臣负责, 但目前还不是博导, 以别人的名义带博士. 目前有板有3-4个
博士. 主要研究两亲性嵌段共聚物. PEO-b-PNIPAM, PEO-b-Pgltycose. and
PS-b-Pglycose PS-b-PEO etc. 还有他们的自组装.产品主要用ATRP, RAFT and 高分字反
映合成. 另外一个老师是杜福胜, 今年从Arkon回国, 主要方向是光敏性高分子的合成.
超分子研究组: 宛新华, 博导. 2002年从周其风组分离出来.
主要研究夜晶高分子和Coil-Rod polymers and their self-assembly behaviors. 主要
用自由机聚合和高分字反应.
光化学组: 由曹维孝带领.博导./ 主要研究 |
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w********h 发帖数: 12367 | 34 刚才在整理我的硬盘(顺便问一下电脑通现在流行硬盘多少个G了?)时,
看到以前down的一个北卡的教学用powerpoint,
上面图示已经表明,五十年高分子材料的时代已经过去,
取而代之的是biomaterials, nanomaterials, and biomimic materials.
恍然想起这个我上个月提的话题以及cashine今天姗姗来迟的回应:
高分子科学,你是这个世纪的伴娘科学?
答案很遗憾,是的,它是。
但不意味着它丧失它的重要性。
高分子科学中高分子物理在1940年到1990年50年间已经构建成功,
剩下的人们在围绕reptation model进行对复杂体系的进攻;
高分子化学随着1995年ATRP的一声炮响沉寂多时,
小打小闹着为着所谓“分子设计”“分子裁剪”贡献着一批
又一批可能有用但更可能无用的block copolymer们。
高分子材料领域套着如今材料科学的东风和众多fancy的
名称如nano, 如photonic,如self-assembly,如supramolecular,
如biomimic继续在fancy的杂志上刊登着一些暂时影响因子硕高, |
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c*s 发帖数: 2145 | 35 so far, most papers I read on this topic involves polymer, not co-polymer.
Most commonly used method is either ATRP or surface grafting of MAA, NIPAM or
VP. due to their responsibility to temperature, pH or metal ions.. |
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c*s 发帖数: 2145 | 36 I agree, either atrp or zigler-natta
it
doing
physicists
Shiley |
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y***e 发帖数: 6082 | 37 据说ysk才是真正搞出ATRP的,被老马抢了,有没有这回事
今年以来已经被引135次,即将突破1000次大关。
another one on Macromolecules got 550 times.
如果工业化了,这个不授Nobel就没天理了。
但愿王锦山同学能搞上一把。。。
当年应圣康不喜欢的弟子,却实实在在为中国人在高分子化学领域争了脸,留了名。
Title: CONTROLLED LIVING RADICAL POLYMERIZATION - ATOM-TRANSFER RADICAL
POLYMERIZATION IN THE PRESENCE OF TRANSITION-METAL COMPLEXES
Author(s): WANG JS, MATYJASZEWSKI K
Source: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 117 (20): 5614-5615 MAY 24
1995
Document Type: Note
Language: English
Cited References: 21 Times C |
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w********h 发帖数: 12367 | 38 我听到的版本是王锦山在比利时读博士的时候就有atrp这个idea,然后
到马先生那里发展了成比较成熟的实验结果。应该说,这个和今天的Linda Buck和
Axel的关系差不多。可惜的是王锦山转入工业界,不晓得有没有机会,还是马先生
和日本的Sawamoto共享。马先生当年对待应先生投macromolecules的文章可谓是
“学霸”作风了。
这个活性聚合最初的idea应该是Szwac...居然没有获Nobel...也满亏的。 |
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c****n 发帖数: 134 | 39 people don't solve all the problems; rather, they leave the real challenge
behind.
1) For ATRP: several papers attempted preparing triblock copolymers as
Thermoplastic elastomers, but without decent properties (I would say results
are lousy).
2) It was claimed in a review "virtually all monomers are polymerized in
living XXXX polymerization". A critical review would add "but only a few are
truly living and in most cases the polydispersity is too large". |
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c*******n 发帖数: 1648 | 42 Is that the same company which commercialized Kennedy's cationatic
polymerization? Faint. |
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c*s 发帖数: 2145 | 43 in your experience? thanks
If I want to speed up the reation, does it work to improve the amount of
catalyst added?
thanks |
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y***e 发帖数: 6082 | 46 今天看了片jacs,5min长100nm,ATRP,感觉怎么这么强,说是用了种新的组合催化剂系
统 |
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