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Macromolecules版 - Hole mobility and conducting polymer
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1 (共1页)
a***n
发帖数: 578
1
Since conducting polymer has similiar conductivity as copper, so I assume its
hole mobility is at same order as electron mobility in metal. Is it right?
thanks. Who studying this pls give some hints. thanks.
l*****o
发帖数: 82
2

Which polymer?
In my memory, most are not. Much much smaller, even with the same conductivity.

【在 a***n 的大作中提到】
: Since conducting polymer has similiar conductivity as copper, so I assume its
: hole mobility is at same order as electron mobility in metal. Is it right?
: thanks. Who studying this pls give some hints. thanks.

a***n
发帖数: 578
3
Thanks for your message.
I think hole mobility in polymer should be related to its conductivity. Why it
is much smaller? I got some data for the hole mobility. The largest is 0.1 ~ 1
cm2/Vs for field effect hole mobility, reponsding to 10 cm2/Vs for defect free
hole mobility.
I am quite confused at all those concepts such as hole drift velocity,
field-effect hole mobility and defect free hole mobility.
I am checking some book talking about them. But still prefer some book
especially talking abou

【在 l*****o 的大作中提到】
:
: Which polymer?
: In my memory, most are not. Much much smaller, even with the same conductivity.

l*****o
发帖数: 82
4
I don't know either. But keep two fact in mind:
1. conductivity is not only the function of mobility, but that of carrier
density.
2. The charge carriers in polymer are not free carrier. Some are polarons, some
are solitons.

【在 a***n 的大作中提到】
: Thanks for your message.
: I think hole mobility in polymer should be related to its conductivity. Why it
: is much smaller? I got some data for the hole mobility. The largest is 0.1 ~ 1
: cm2/Vs for field effect hole mobility, reponsding to 10 cm2/Vs for defect free
: hole mobility.
: I am quite confused at all those concepts such as hole drift velocity,
: field-effect hole mobility and defect free hole mobility.
: I am checking some book talking about them. But still prefer some book
: especially talking abou

d***l
发帖数: 48
5
The high conductivity CP is in the doped state, in which bipolaron is the
charge carrier.
The neutral form of CP is the semiconductor. In the case of CP, I think
poly(3-alkylthiophene) has the highest hole mobility.

its

【在 a***n 的大作中提到】
: Since conducting polymer has similiar conductivity as copper, so I assume its
: hole mobility is at same order as electron mobility in metal. Is it right?
: thanks. Who studying this pls give some hints. thanks.

a***n
发帖数: 578
6

some
It helps. thanks.
Why it
~ 1
free

【在 l*****o 的大作中提到】
: I don't know either. But keep two fact in mind:
: 1. conductivity is not only the function of mobility, but that of carrier
: density.
: 2. The charge carriers in polymer are not free carrier. Some are polarons, some
: are solitons.

a***n
发帖数: 578
7
thanks.

You are right at the polymer which has the highest hole mobility.
FYI, there is another type polymer called instinc conducting polymer that
doesn't require dopant.

【在 d***l 的大作中提到】
: The high conductivity CP is in the doped state, in which bipolaron is the
: charge carrier.
: The neutral form of CP is the semiconductor. In the case of CP, I think
: poly(3-alkylthiophene) has the highest hole mobility.
:
: its

1 (共1页)
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