f**********e 发帖数: 1994 | 1 CASSCF 的能量通常不太准,如果开错 active space, 那结果会很操蛋。
我以前这样干过:先用 CI 扫优化构型附近,看看 low-lying 的 excited
states 是不是都是一个 configuration 独大的,如果是,我就把 Hartree
Fock 的 occupied 换一换,就变成 excited state 了。那时你想用
CCSDT 高阶方法还是优化 excited state 构型随便你。
如果 excited state 是一堆 Slater det 混出来的... 那就祝好运了。 |
|
T*******y 发帖数: 6523 | 2 Why is getting the green card not as exciting as getting the 140 approved?
http://www.youtube.com/watch?v=axrywDP9Ii0&feature=youtu.be
It's dopamine that brings the feeling of excitement. Uncertainty sends dopamine skyrocketing. The 50% approval rate of EB1A makes the perfect cocktail for the brain that's craving that dopamine fix, just like romantic love, or other pursuits. The pursuit itself is what makes the journey exciting, rather than the final reward. |
|
p***y 发帖数: 18037 | 3 Best of NYC Dining: 10 Most Exciting Restaurants
By the editors, with Adeena Sussman, Jocelyn C. Zuckerman
and Joshua
David Stein | Manhattan magazine | July 12, 2010
http://manhattan.modernluxury.com/dining/best-nyc-dining-10-most-exciting-restaurants
BETTER WITH AGE
The staff and its manager Charles Masson (in dark
suit, left), unwind after close at La Grenouille—
a timeless classic
and blueprint for how to keep things exciting
after five decades. |
Photo by Ben Pier |
|
h*h 发帖数: 27852 | 4 【 以下文字转载自 Love 讨论区 】
发信人: wzyan (悠悠), 信区: Love
标 题: 我的美国男朋友说最喜欢我能bring a lot of fun and excitement
发信站: BBS 未名空间站 (Sat Feb 13 14:47:09 2010, 美东)
喜欢申讨外f的注意了,这里又有你们最喜欢的活生生的教材了亚!
我们在一起一年半。我们天天腻在一起,像大学校园恋那时那样。
他说他can't live without excitement. 他说我们之间充满了passion和fun。
他是个非常聪明的人,而且精力充沛,我其实常常有点累。
我知道他不stable,不够体贴,不做家务。虽然年入百万但是都是凭他那点聪明,他并
不是很勤奋的那种人。
虽然我们在一起真的是很happy和fun,但是我是个女生,真的要这样一辈子吗?
更别提他像个animal一样的sex drive阿。虽然我可以keep up,但是我总担心,哪天跟
不上他的步伐了,就会被cheat得很惨哪。
其实我一直觉得自己是挺向往稳定简单的幸福。为什么给他的印象却是fun和exciting
呢 |
|
d****n 发帖数: 397 | 5 你要先知道基态的能量,还有那个dissociation 对应的是哪个激发态。
这样先做对基态做一个构型优化,得到基态的能量,
然后,做TD,或者CIS,就能算出vertical excitation所需要的波长。
这个其实不是所需要的最短波长,可是根据Frank-Condon原理,是吸收的cross-
section最大的波长,也就是photodissociation所需要的波长。
你查查文献,看看那个photodissociation对应的是哪个excited state,假设对应的是
第一个excited state
那CIS的输入就是:
%chk=test.chk
#p cis uhf/basis gfinput geom=check guess=read
photodissociation
0,2
还有写gaussian输入时候,最后一行一定要是空行。
因为你的是open shell (radical) system,那些singlet,triplet keywords你不用关心。
如果用TDDFT的话,应该是#p td ub3lyp/basis geom=check gues... 阅读全帖 |
|
m******e 发帖数: 44 | 6 Let's say, we have a rectangular waveguide, with one end shorted, and the
other end with absorbing boundary, in the middle of the waveguide, we have a
incident plane wave excitation. So how should we model this incident plane
wave excitation numerically? by equivalent surface magnetic current density?
or use a total = incident + scattering fields decomposition, with the total
field solved on the side of shorted end and scattered field on the open end
? I did not get reasonable results either way... 阅读全帖 |
|
h*h 发帖数: 27852 | 7 【 以下文字转载自 Love 讨论区 】
发信人: wzyan (悠悠), 信区: Love
标 题: 我的美国男朋友说最喜欢我能bring a lot of fun and excitement
发信站: BBS 未名空间站 (Sat Feb 13 14:47:09 2010, 美东)
喜欢申讨外f的注意了,这里又有你们最喜欢的活生生的教材了亚!
我们在一起一年半。我们天天腻在一起,像大学校园恋那时那样。
他说他can't live without excitement. 他说我们之间充满了passion和fun。
他是个非常聪明的人,而且精力充沛,我其实常常有点累。
我知道他不stable,不够体贴,不做家务。虽然年入百万但是都是凭他那点聪明,他并
不是很勤奋的那种人。
虽然我们在一起真的是很happy和fun,但是我是个女生,真的要这样一辈子吗?
更别提他像个animal一样的sex drive阿。虽然我可以keep up,但是我总担心,哪天跟
不上他的步伐了,就会被cheat得很惨哪。
其实我一直觉得自己是挺向往稳定简单的幸福。为什么给他的印象却是fun和exciting
呢 |
|
c********n 发帖数: 2166 | 8 【 以下文字转载自 USANews 讨论区 】
发信人: crossocean (过海兵), 信区: USANews
标 题: 原来魏京生是中国愤青(excited patriotic Chinese)
发信站: BBS 未名空间站 (Thu Jan 27 01:07:15 2011, 美东)
朗朗演奏事件闹得好不热闹,我太八卦了,想查查哪里最先闹起来的。
最著名的是魏京生21日发给国会的公开信,说“excited "patriotic Chinese" have
already written their comments such as: ‘the right place, right time, right
song!’on Internet”
好了,我到中国去寻21日之前的网评,找了好久,找到几个在21日前发布朗朗在白宫演
奏“我的祖国”消息的,可看那些网评,多是嘲讽朗朗的,比如
http://www.chinaelections.org/NewsInfo.asp?NewsID=198176
问题来了,照魏京生意思,21日之前激动的中国愤青已经为朗朗欢呼,可我却偏寻不到
,反... 阅读全帖 |
|
c********n 发帖数: 2166 | 9 【 以下文字转载自 USANews 讨论区 】
发信人: crossocean (过海兵), 信区: USANews
标 题: 原来魏京生是中国愤青(excited patriotic Chinese)
发信站: BBS 未名空间站 (Thu Jan 27 01:07:15 2011, 美东)
朗朗演奏事件闹得好不热闹,我太八卦了,想查查哪里最先闹起来的。
最著名的是魏京生21日发给国会的公开信,说“excited "patriotic Chinese" have
already written their comments such as: ‘the right place, right time, right
song!’on Internet”
好了,我到中国去寻21日之前的网评,找了好久,找到几个在21日前发布朗朗在白宫演
奏“我的祖国”消息的,可看那些网评,多是嘲讽朗朗的,比如
http://www.chinaelections.org/NewsInfo.asp?NewsID=198176
问题来了,照魏京生意思,21日之前激动的中国愤青已经为朗朗欢呼,可我却偏寻不到
,反... 阅读全帖 |
|
S*********g 发帖数: 24893 | 10 【 以下文字转载自 Stock 讨论区 】
发信人: StephenKing (金博士), 信区: Stock
标 题: 炒股觉得excited的,大多赔钱,还赔的不少。比如小小人版主。
发信站: BBS 未名空间站 (Mon Nov 12 11:11:42 2018, 美东)
炒股觉得boring的,大多挣钱,还挣的不少。
炒股觉得excited的,大多赔钱,还赔的不少。比如小小人版主。
27岁定投SP,投到67岁。一辈子只操作一次。结果都不错。
每个月定存1000,SP平均7%的年增长。40年后退休的时候48万的本金变成300万。 |
|
g****t 发帖数: 31659 | 11 【 以下文字转载自 History 讨论区 】
发信人: guvest (我爱你老婆Anna), 信区: History
标 题: 江core:你们给我搞的这个东西,excited!
发信站: BBS 未名空间站 (Sat Oct 29 21:51:23 2011, 美东)
http://v.youku.com/v_show/id_XMjMzNDQyOTA4.html
v.youku.com/v_show/id_XMjMzNDQyOTA4.html
片段最后,江core突然大喊:"excited".
我怀疑他退休生活是不是天天看美国电视,跟我们类似. |
|
g****t 发帖数: 31659 | 12 【 以下文字转载自 History 讨论区 】
发信人: guvest (我爱你老婆Anna), 信区: History
标 题: 江core:你们给我搞的这个东西,excited!
发信站: BBS 未名空间站 (Sat Oct 29 21:51:23 2011, 美东)
http://v.youku.com/v_show/id_XMjMzNDQyOTA4.html
v.youku.com/v_show/id_XMjMzNDQyOTA4.html
片段最后,江core突然大喊:"excited".
我怀疑他退休生活是不是天天看美国电视,跟我们类似. |
|
c****n 发帖数: 1108 | 13 【 以下文字转载自 Joke 讨论区 】
发信人: MVPYao (退役了 | Hall of Famer), 信区: Joke
标 题: 老太婆高兴坏了:Hillary got a little bit too excited (转载)
发信站: BBS 未名空间站 (Fri Jul 29 09:54:08 2016, 美东)
发信人: MVPYao (退役了 | Hall of Famer), 信区: USANews
标 题: 老太婆高兴坏了:Hillary got a little bit too excited
发信站: BBS 未名空间站 (Fri Jul 29 09:52:08 2016, 美东) |
|
g****t 发帖数: 31659 | 14 Excitment is guaranteed!
这是格林厄姆书的最后一句话。
我认为他的意思是:一进股市,除了excitment,其他的都不保证! |
|
D*******e 发帖数: 12862 | 15 其实对我来说
最exciting的是nba playoffs & Monte Carlo both will start on 4/15~~
Most exciting part of the season for me :)
go spurs~~
go rafa~~ |
|
c*******s 发帖数: 1555 | 16 why shouldn't we be excited? I think Meyer will put together a great coach
group, and with all the talents in the program, we have every reason to be
excited. |
|
n*******1 发帖数: 2254 | 17 whatever,I'm just excited finally bollman will be gone.
maybe you should change your topic to "why a vt fan get so excited about Mr
Meyer? cuz Mr Meyer is overrated!" haha |
|
l*********e 发帖数: 5483 | 18 俺的标准不高:
~6w satisfied
~8w happy
~10w excited
so 按照俺的这个标准我预计雀斑的90%以上的都已经相当excited了?
俺这个标准是基于这样的理解:
我来美国的那年年底我们组的师兄毕业。他年薪当时大约8w多的,现在10w多了,这五年期间他买了新房子(近30w),购置三两新车,又生了一个孩子,共两孩子,供孩子上各种培训班。我听说他的这个收入在当地属于middle-up level了。
注: 该地是个小地方。 |
|
U**R 发帖数: 400 | 19 My ZIndo calculation gives me the excitation energies. I know experimentally
the S1-->S0 energy. So, should I shift all the excitation energies, or
should I scale them? |
|
|
c****a 发帖数: 2421 | 21 写字写着写着把外衣脱了,大喊一声excited! |
|
b******n 发帖数: 4225 | 22 才帝没有唱歌啊
不过那个excited确实霸气外露 |
|
c******i 发帖数: 4091 | 23 Love wins, HIV/AIDS excites, and Darwin rules. hehe |
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B*G 发帖数: 13438 | 24 不知道江core坐进j10的时候是不是也这么喊了一嗓子,这语法是绝地武士的吧,"
excited, i am" |
|
B*G 发帖数: 13438 | 25 不知道江core坐进j10的时候是不是也这么喊了一嗓子,这语法是绝地武士的吧,"
excited, i am" |
|
c********n 发帖数: 2166 | 26 朗朗演奏事件闹得好不热闹,我太八卦了,想查查哪里最先闹起来的。
最著名的是魏京生21日发给国会的公开信,说“excited "patriotic Chinese" have
already written their comments such as: ‘the right place, right time, right
song!’on Internet”
好了,我到中国去寻21日之前的网评,找了好久,找到几个在21日前发布朗朗在白宫演
奏“我的祖国”消息的,可看那些网评,多是嘲讽朗朗的,比如
http://www.chinaelections.org/NewsInfo.asp?NewsID=198176
问题来了,照魏京生意思,21日之前激动的中国愤青已经为朗朗欢呼,可我却偏寻不到
,反而找到嘲讽朗朗的。那这个“网上的一些中国愤青已经有评语:正确的地方,正确
的时间,正确的歌!”来自哪里?
美国为抗英谱写的星条旗歌在英白金汉宫演唱不知多少次了,没听英女王说过被耻辱。
文革红卫兵的一大特色是上纲上线,把什么都扯到政治解读,这也是愤青的一大特色,
在这里我只看见魏京生是第一个把朗朗演... 阅读全帖 |
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l****z 发帖数: 29846 | 27 By Susan Jones
June 7, 2012
(CNSNews.com) - As part of a fundraising effort, the Democratic Senatorial
Campaign Committee is offering "a trip for two" to watch President Obama
speak at the 2012 Democratic National Convention in Charlotte, N.C.
The trip could be yours -- "if you contribute $5 now," Sen. Patty Murray
says in an email pitch. Murray, a Washington Democrat, chairs the DSCC.
"I think everyone remembers where they were when President Obama accepted
the 2008 nomination. That speech will... 阅读全帖 |
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c******i 发帖数: 4091 | 28 Love wins, HIV/AIDS excites, and Darwin rules. hehe |
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c****n 发帖数: 1108 | 29 【 以下文字转载自 Joke 讨论区 】
发信人: dakedo (大蝌蚪), 信区: Joke
标 题: Re: 老太婆高兴坏了:Hillary got a little bit too excited (转载
发信站: BBS 未名空间站 (Fri Jul 29 10:43:56 2016, 美东)
是不是真的健康出问题了
跟之前那次有点像 |
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t*******h 发帖数: 2744 | 30 但她性格中的可贵之处在她的resilience。她是人,会生病会失败会被人讨厌,但不管
怎样跌倒了她总能爬起来坚持下去,这难道不也正是她最能让人动容最能带给人
excitement的地方吗?她的选民会对她不离不弃,她的选情和她的健康她的人生一样,
会有风波挫折,但始终都会是tough and solid. |
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c***2 发帖数: 838 | 31 Started looking 3 months ago, did 4 onsites so far,
got 2 offers in last 2 months.
1) 8% base increase from a small company (rejected)
2) 12% base increase from a mid-size company (still alive)
(Both companies are not famous)
They all do similar things as my current job.
But I am not excited at all.
Am I too old?
Not sure whether I shall accept the 2nd or continue looking... |
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B*******1 发帖数: 2454 | 32 You need some change to make you excited. |
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P*****a 发帖数: 2464 | 33 你不是自己很明白么
1.increase is not significant
2.companies are not great (maybe they are, cannot tell from your tone)
3. do similar things as your current job
这换了别人估计也不是很excited,嘿嘿 |
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c***2 发帖数: 838 | 34 I guess this is common when you are getting old...
A job is just a job, you will never repeat the excitement from your first
job right out of school. |
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p*********8 发帖数: 957 | 35 I guess it is too easy for you to get this job, If you dont have money and
need a job badly, you will be very excited |
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p****j 发帖数: 4762 | 36 why needs to be excited? |
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f*****e 发帖数: 10 | 37 We are looking for talented people with background in financial services -
wealth management, risk management, data analysis and IT to join a fast-
growing company CreditEase (宜信). People will Wall Street experience are
especially welcome. CreditEase is based in Beijing and founded by PKU
alumni Mr. Ning Tang and recently it has attracted quite a few outstanding "
sea turtles". It's the market leader in micro-finance industry in China and
is expanding to many areas in financial services such ... 阅读全帖 |
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o*********l 发帖数: 1807 | 38 I know it is exciting to see a big drop today but get yourself together and
decide what do you want to do for 1-3 months. |
|
j******m 发帖数: 3259 | 39 It might be exciting for a couple of days, but may not be as many as people
believe.
today |
|
l******c 发帖数: 2555 | 40 not an exciting day, it's a desperate day, dump UD$ in any way
CAF up 4%, SLV up 5%
all time high
for chinese americans, today is a depressed day
today |
|
m*****i 发帖数: 4342 | 41 I do have a small position of HPQ, slightly underwater right now.
I still think MSFT will be exciting in the second half this year.
BTW, I am bullish on Solar now, and long LDK and YGE today:) |
|
c*********l 发帖数: 926 | 42 【 以下文字转载自 JobHunting 讨论区 】
发信人: crystalbull (牛), 信区: JobHunting
标 题: Pure Storage IPO Fails To Excite Investors In Debut
发信站: BBS 未名空间站 (Wed Oct 7 12:06:59 2015, 美东)
我觉得pure storage过半年后股价会跌到IPO价格的一半.跟BOX一个套路. |
|
S*********g 发帖数: 24893 | 43 炒股觉得boring的,大多挣钱,还挣的不少。
炒股觉得excited的,大多赔钱,还赔的不少。比如小小人版主。
27岁定投SP,投到67岁。一辈子只操作一次。结果都不错。
每个月定存1000,SP平均7%的年增长。40年后退休的时候48万的本金变成300万。 |
|
k******n 发帖数: 1265 | 44 499!!!
这个还比较exciting!!! |
|
k******n 发帖数: 1265 | 45 499!!!
这个还比较exciting!!! |
|
s******y 发帖数: 121 | 46
An easy but dangerous route. A lot of loose rocks, which is no fun at all. I
'd rather climb Longs Peak, casual route if I can find a partner, or just
solo Kiener's route. The broadway traverse is exciting. |
|
W***n 发帖数: 11530 | 47
No, not right now. Only vacationed couple of times there. I like the Rockies
a lot.
If you like challenged and exciting climbing, send me your email. I shall
let you know when and where my ascents will be in the future..
Right now, I am living only few hundred feet above see level :-( |
|
g*********d 发帖数: 203 | 48 呵呵....多谢了。看见你的challenged and exciting climbing就已经很期待了。
Rockies |
|
Y***r 发帖数: 15270 | 49 【 以下文字转载自 Military 讨论区 】
发信人: celica (一江春水向东流), 信区: Military
标 题: 江靠大喊excited!
发信站: BBS 未名空间站 (Fri Oct 28 17:54:42 2011, 美东) |
|
Y***r 发帖数: 15270 | 50 从9分开始看,题字的时候突然脱掉外衣大喊一声 excited ! |
|