O*******f
发帖数: 926 | 1 model:
CH3- + CH3ONa ---> CH4 + -CH2ONa
possible example:
CH3MgI + CH3ONa ---> CH4 + IMgCH2ONa
CH3Li + CH3ONa ---> CH4 + LiCH2ONa
有意思，感觉Li的那个正向有可能，可溶剂选谁？
有没有搞计算的童鞋？ |
|
r******0
发帖数: 2753 | 2 be careful when handle Na. Trace amount of water is fine. But if I were you,
I would use CH3ONa instead. Mix CH3ONa and C4H9OH first and distill CH3OH
out, then add the polymers in. Wish you good luck on the experiment. |
|
a*****h
发帖数: 13 | 3 t-butyl ester group seems to be quite stable in basic conditions, while not
stable in acidic conditions. I once tried to remove the t-butyl groups by
CH3ONa it didnot work, or very less amount of tButyl groups were destroyed |
|
